a powerful analytical techniqueIon Chromatography (IC) Testing for PCB Reliability

Ion chromatography characterizes and quantifies specific residue species present on samples. Performed in accordance with the latest IPC standards, ZESTRON offers both “full” board and localized” spot extraction techniques to identify the presence of undesired ionic materials.  The testing can be performed on bare PCB components and fully populated PCBAs.  Identifying ionic residues and understanding trouble areas will lead to improved product quality.

ion chromatography testing machine for circuit boards

Ion chromatography "Full" Board Extraction Technique

"Full" board extraction provides the average of all ionic contaminants on the board surface. It aims to analyze the ionic species on the board surface and assess its overall cleanliness level. As one of the electronics industry's most widely used test methods to quantitatively identify and measure ionic (anions, cations, WOAs) specifies present on the board surface that could ultimately lead to in-field board failures.

ion chromatography "Localized" Spot Extraction Technique

“Localized” extraction, unlike “full” board extraction, targets critical areas of concern (0.1 in2) on the board surface to assess cleanliness levels.  It can be used to perform electrical tests that provide immediate “clean” or “dirty” readings for ionic contamination.  Additionally, the extracted sample can be subjected to IC testing to quantify ionic residues.  Therefore, “localized” ion chromatography can be tailored to individual test points for further investigation of ionic contamination within targeted troublesome areas.

c3 ion chromatography testing machine for circuit boards


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Frequently Asked Questions (FAQ) – Ion Chromatography Testing & Analysis

 

Ion Chromatography (IC) is a high‑resolution analytical technique used to quantitatively and qualitatively identify ionic species (anions, cations, and weak organic acids) on circuit boards and assemblies. It detects specific residue ions that may cause electrical issues such as corrosion, leakage current, or electrochemical migration.

IC testing helps manufacturers assess surface cleanliness and contamination at a detailed level, providing insights into potential failure mechanisms and enabling risk‑based process optimization to improve product quality and long‑term reliability.

Unlike simpler methods like ROSE tests that give only a total ionic contamination value, IC delivers a precise breakdown of specific ions present, helping identify the exact causes and types of contaminants on the board surface.

Ion Chromatography can be performed on bare PCBs and fully assembled PCBAs using both “full board” extraction and localized spot extraction techniques to focus on critical areas of concern.

IC testing can uncover issues such as critical ion contamination, hygroscopic ion accumulation (e.g., chloride or bromide), weak organic acids, and moisture‑induced risks — all of which can lead to field failures if left unaddressed.

The detailed ion profiles from IC testing support cleaning process evaluations, surface qualification, process troubleshooting, yield improvement, and reliability verification prior to coating, bonding, or critical assembly steps.